Disc I
01. Elf - Carolina County Ball
02. Roger Glover & Friends - Love Is All
03. Rainbow - The Temple Of The King
04. Rainbow - Catch The Rainbow
05. Rainbow - Stargazer
06. Rainbow - Run With The Wolf
07. Rainbow - Kill The King [live]
08. Rainbow - Long Live Rock 'N' Roll
09. Rainbow - Lady Of The Lake
10. Rainbow - Gates Of Babylon
11. Black Sabbath - Die Young
12. Black Sabbath - Heaven And Hell
13. Black Sabbath - Children Of The Sea

Disc II
01. Black Sabbath - The Mob Rules
02. Black Sabbath - Voodoo
03. Black Sabbath - Country Girl
04. Dio - Holy Diver
05. Dio - Rainbow In The Dark
06. Dio - We Rock
07. Dio - Rock 'N' Roll Children
08. Dio - All The Fools Sailed Away
09. Black Sabbath - I
10. Dio - Push
11. Dio - One More For The Road
12. Black Sabbath - Shadow Of The Wind
13. Heaven & Hell - Neon Knights [live]
14. Heaven & Hell - Bible Black

Additional info
This is the second such Dio career compilation that covers from Elf onwards, but the first to cover music from the Heaven & Hell era.
This release has several bits inside the liner notes about the RJD "Stand Up & Shout" Cancer Fund in it.
The artwork on the back cover of the CD insert is called Fall of the Rebel Angels from 1562 by Peter Brueghel.