Disc I [Black Sabbath]
01. Black Sabbath
02. The Wizard
03. Wasp / Behind The Wall Of Sleep / Bassically / N.I.B.
04. Wicked World
05. A Bit Of Finger / Sleeping Village / Warning
06. Evil Woman

Disc II [Paranoid]
01. War Pigs
02. Paranoid
03. Planet Caravan
04. Iron Man
05. Electric Funeral
06. Hand Of Doom
07. Rat Salad
08. Fairies Wear Boots

Disc III [Master Of Reality]
01. Sweet Leaf
02. After Forever
03. Embryo
04. Children Of The Grave
05. Orchid
06. Lord Of This World
07. Solitude
08. Into The Void

Disc IV [Volume 4]
01. Wheels Of Confusion / The Straightener
02. Tomorrow's Dream
03. Changes
04. FX
05. Supernaut
06. Snowblind
07. Cornucopia
08. Laguna Sunrise
09. St. Vitus' Dance
10. Under The Sun / Every Day Comes And Goes

Disc V [Sabbath Bloody Sabbath]
01. Sabbath Bloody Sabbath
02. A National Acrobat
03. Fluff
04. Sabbra Cadabra
05. Killing Yourself To Live
06. Who Are You
07. Looking For Today
08. Spiral Architect

Disc VI [Sabotage]
01. Hole In The Sky
02. Dont' Start (Too Late)
03. Symptom Of The Universe
04. Megalomania
05. The Thrill Of It All
06. Supertzar
07. Am I Going Insane (Radio)
08. The Writ

Disc VII [Technical Ecstasy]
01. Back Street Kids
02. You Won't Change Me
03. It's Alright
04. Gypsy
05. All Moving Parts (Stand Still)
06. Rock n' Roll Doctor
07. She's Gone
08. Dirty Women

Disc VIII [Never Say Die!]
01. Never Say Die
02. A Hard Road
03. Junior's Eyes
04. Shock Wave
05. Johnny Blade
06. Air Dance
07. Breakout
08. Swinging The Chain
09. Over To You

Disc IX [DVD]
01. Black Sabbath [live]
02. Paranoid [live]
03. Iron Man [live]
04. Blue Suede Shoes [live]

Additional info
The songs on the DVD are more commonly known "The Beat Club Footage". It's been available before elsewhere, but the version on Black Box looks to have been visually cleaned up like the audio discs have, too. There is no further content on the DVD.